A Switchable Palladium(II) Trefoil Entangled Tetrahedron with Temperature Dependence and Concentration Independence
نویسندگان
چکیده
Self-assembly makes metallo-interlocked architectures attractive targets, but being in equilibrium with smaller species means that they can suffer from dilution effects. We show a junctioned system gives rise to [Pd4(L)2]8+ trefoil entangled tetrahedron irrespective of concentration. Heating the sample reversibly shifts knot an isomeric non-interlocked dual metallo-cycle, demonstrating thermodynamic equilibria still be exploited for switching even absence concentration
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2022
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/ange.202210476